Characterization techniques
Characterization of organic materials

Characterization of organic materials

Rrganic materials play an essential role in understanding ancient objects, whether it's a question of identifying component (binders, varnishes, waxes) or organic residues absorbed into archaeological objects.

CIRAM combines different techniques depending on the type of material and the objective of the analysis:

  • Raman and FTIR spectroscopy (non-destructive): allows for rapid identification of chemical families without altering the object.
  • Gas chromatography-mass spectrometry (GC-MS): ideal for breaking down and characterizing complex mixtures (old varnishes, binders, waxes, etc.).
  • Elemental and isotopic analysis (EA-IRMS): to trace the organic origin (plant or animal) of a material and quantify its biobased content, particularly in the context of ISO 16620-2.

Analyses are carried out on micro-samples (a few milligrams), with great precision.

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Organic materials characterization applications

01 - Study of organic residues in archaeology

The analysis of organic residues on artifacts (ceramics, tools, ritual objects) allows for the reconstruction of ancient practices: diet, body treatment, rituals, and craftsmanship. By identifying compounds such as fatty acids, resins, waxes, or proteins, archaeologists gain access to valuable functional information about past civilizations.

  • GC-MS and FTIR are the reference methods for revealing and identifying these minute traces.
  • EA-IRMS allows confirmation of the plant or animal origin of certain compounds.
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02 - Authentication and conservation of works of art

The binders, varnishes, and waxes used in artworks are chemical markers revealing an era, a workshop, or a restoration. CIRAM identifies these materials and compares them to internal and scientific databases to detect inconsistencies or modern restorations.

  • These analyses can help to authenticate a work, identify an original pictorial technique, or detect undocumented later additions.
  • They also guide restorers in the choice of materials compatible with the object.
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Microanalysis of stones, glass and pigments

Microanalysis consists of studying the chemical and mineralogical composition of materials at the microscopic scale. It allows for the identification of the constituent elements of stones, glasses, ceramics, pigments, and mineral deposits, and for understanding their origin, transformation, and alteration.

At CIRAM, this approach relies on high-resolution analytical instruments such as:

  • Scanning electron microscope coupled with energy-dispersive spectrometry (SEM-EDX),
  • Inductively coupled plasma mass spectrometry(ICP-MS),
  • X-ray diffraction (XRD),
  • Raman spectroscopy.

CIRAM uses microanalysis in projects involving authentication, conservation-restoration, archaeometry and the industrial traceability of materials.

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Microanalysis characterization applications

01 - Study of origins and manufacturing techniques

Thanks to the chemical signature of a material, it is possible to trace its geological origin or reconstruct the manufacturing processes used. This data is essential for:

  • Identify a workshop or production area,
  • Detect mixtures or imitations,
  • Understand the technical choices made by ancient craftsmen.

02 - Analysis of weathering and deposits

Archaeological objects often present mineral deposits (crusts, efflorescences, patinas), the nature of which provides information about their conservation environment. CIRAM analyzes these layers to:

  • Assess weathering processes,
  • Guide conservation decisions,
  • Understand the interactions between the object and its environment.
Ancient Indian copper artifact

Metallographic characterization

The Metallography enables in-depth study of the composition, structure and manufacturing processes of ancient metal objects. It is essential for identifying alloys, detecting modern elements, analyzing patinas and understanding alterations.

At CIRAM, this analysis relies on complementary techniques:

  • SEM-EDX (Scanning Electron Microscopy with Energy Dispersive Spectrometry), to visualize the microstructure and map chemical elements at high resolution,
  • ICP-MS (inductively coupled plasma mass spectrometry), to detect and quantify trace elements, often crucial for authentication.

This approach allows to authenticate an object, to characterize its manufacturing, and to guide conservation or expertise actions, by cross-referencing chemical and historical data.

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Metallographic characterization applications

01 - Copper, silver, brass

For copper alloys (bronze, brass) or silver objects, metallography can detect exogenous elements often indicative of modern manufacturing, such as aluminum, chromium, or manganese. These markers, absent in ancient alloys, frequently betray recent production or an attempt at counterfeiting.

The analysis of the patina, whether natural (formed over the long term by atmospheric corrosion) or artificial (created by chemical processes), reveals valuable chronological clues for dating an ancient work.

Finally, the study of the metal's microstructure can reveal the shaping techniques: casting, hammering, annealing, or welding.

02 - Iron and gold

Iron objects present particular challenges due to their high sensitivity to corrosion. Metallography therefore focuses on the analysis of non-metallic inclusions and internal impurities, which are indicative of ancient forging processes. The absence of certain treatments or the presence of characteristic inclusions makes it possible to distinguish between ancient artisanal production and a modern object.

For gold, a metal little subject to oxidation, characterization relies on the detection of trace elements (lead, bismuth, tin, etc.), whose concentrations can betray a chronological or geographical origin. This data is decisive in the attribution, appraisal, or certification of works in precious metals.

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Laboratoires CIRAM, world leader in characterization

For over two decades, CIRAM has established itself as a key player in the scientific analysis of ancient materials, both in the art market and in the sectors of archaeology and industry. Its expertise is based on a unique combination of scientific rigor, state-of-the-art analytical equipment, and a multidisciplinary team of PhDs in physics, chemistry, geosciences, and materials.

Each analysis project benefits from a tailor-made protocol, designed to meet the client's specific challenges: study of the conservation of a work of art, indirect dating, corrosion study, or validation of an industrial process.

Recognized by museum institutions, auction houses, excavation operators, and industrialists, the CIRAM approach guarantees analytical reliability and clarity of results that are now a benchmark in Europe and internationally.

Are you asking yourself these questions?

What is materials characterization?

The characterization of materials involves analyzing their chemical composition, structure and state of preservation in order to determine their origin, manufacture and age.

What types of materials can be analyzed?

Our laboratories study a wide variety of materials, including ceramics, stone, glass, metals, wood, ivory, paper and antique textiles.

Why is characterization essential?

It allows us to identify the origin of materials, analyze manufacturing techniques and establish chronologies, thus providing a better understanding of the artifacts.

What are the main techniques used in characterization?

We use scanning electron microscopy (SEM-EDX), Raman spectrometry and X-ray diffraction.

How long does it take to get the results of a characterization?

Analysis times vary according to the nature of the object and the techniques used. On average, an analysis can take from a few days to several weeks. A precise timetable is provided at the time of acceptance.

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