Analysis of organic materials

Characterization of organic materials

CIRAM performs the analysis of organic materials present in works of art, archaeological artifacts, and industrial materials: varnishes, residues, waxes, binders.

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A scientist taking a sample from a wooden statue

Characterizing organic materials:
essential expertise for art, archaeology and industry

The analysis of organic materials aims to identify, by chemical or isotopic means, substances of natural or synthetic origin present in a heritage object or an industrial material. This characterization technique primarily targets:

  • The organic residues absorbed or deposited (fats, oils, waxes, proteins);
  • The binders and varnishes used in the paint layers or finishes;
  • Bio-based compounds used in the formulation of industrial polymers.

In the art market, it allows for the evaluation of an object's historical and technological consistency or the authentication of a work. In archaeology, it provides functional information on past uses (containers, rituals, techniques). In an industrial context, it offers guarantees on the composition, origin, or conformity of a material.

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Unrolling a papyrus scroll to verify the authenticity of the artwork

Means used to characterize organic materials

CIRAM employs several complementary methods, selected according to the nature of the samples and the study objectives:

  • The Raman spectroscopy, particularly suitable for identifying polymers, resins, waxes, or varnishes, directly on the object or from a micro-sample.
  • FTIR (Fourier Transform Infrared) spectroscopyallows for the rapid identification of functional groups present in organic compounds. Effective for complex mixtures and degraded materials.
  • Gas chromatography-mass spectrometry (GC-MS) analyzes organic mixtures in depth (natural resins, oils, binders, waxes) and allows for comparison with reference databases.
  • Elemental analysis coupled with isotope ratio mass spectrometry (EA-IRMS) provides the isotopic signatures of carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N). This method is used to determine the biological origin of a material or to assess the biobased content according to ISO 16620-2.

These methods can be used alone or in combination to obtain robust results that can be exploited in a heritage or industrial context.

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Residues, binders, varnishes :
materials with a high index value

01 - Organic residues on archaeological objects

In the field of archaeology, organic residues absorbed or embedded on ceramics, tools, or ritual objects offer valuable information about past uses:

  • Nature of products contained (oils, resins, fats, etc.),
  • Processing and preservation methods,
  • Exploited plant or animal sources.

Thanks to GC-MS analysis or FTIR, CIRAM helps archaeologists reconstruct the food, medicinal, or artisanal practices of ancient civilizations.

02 - Binders and varnishes in works of art

In the art market, identifying binders or varnishes (natural resins, drying oils, waxes, animal glues) makes it possible to authenticate works and date their creation. Certain chemical signatures are indeed characteristic of specific periods, geographical areas, or workshops.

Raman or FTIR spectra make it possible to identify these components, and their study compared to historical reference databases refines the analysis.

03 - Industrial waxes and bio-based materials

For industry, and particularly in the packagingsectors, textiles, or polymers, elemental and isotopic analysis (EA-IRMS) allows for:

  • Check the natural or synthetic origin of materials,
  • Determine the bio-based content (particularly according to standard ISO 16620-2),
  • Check product compliance with regulatory or environmental requirements.

CIRAM, expert in organic materials analysis

When you call on CIRAM for your organic analyses, you benefit from recognized expertise, scientific rigor and cutting-edge analytical technologies.
CIRAM relies on :

  • Some highly sensitive and complementary instruments (Raman, IRTF, GC-MS, EA-IRMS),
  • Reference databases for reliable spectrum interpretation,
  • A multidisciplinary team capable of combining different techniques – spectrometry, microanalysis, metallography, chromatography, X-ray radiography – to offer a rigorous and contextualized interpretation of the results.
  • Validated protocols to guarantee the reproducibility and traceability of results.

CIRAM supports museum institutions, archaeologists, auction houses, art restorers, and industrialists in their projects in France and internationally.

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Are you asking yourself these questions?

Is it possible to analyze a varnish on an old painting?

Yes, FTIR or GC-MS analysis can identify the exact nature of the varnish, whether natural (dammar, mastic...) or synthetic.

Can a wax be authenticated?

Yes, chromatographic analysis identifies its composition (bee, carnauba, synthetic...) and can reveal its origin or use.

Does this technique damage the object being analyzed?

No. The methods are non-destructive or require only a micro-sample (<1 mg) depending on the case.

Is it possible to authenticate a work of art using organic analysis?

Yes, binders and varnishes are reliable indicators of any anachronisms or chemical signatures specific to a particular period.

How much does an analysis of organic materials cost?

The cost depends on the number of techniques used, the type of object, the nature of the sample and the degree of interpretation required. Contact us for a personalized quote.

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