Analysis of organic materials

Characterization of organic materials

CIRAM analyzes organic materials present in works of art, archaeological artifacts and industrial materials: varnishes, residues, waxes, binders.

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A scientist taking a sample from a wooden statue

Characterizing organic materials:
essential expertise for art, archaeology and industry

The aim of organic materials analysis is to identify, by chemical or isotopic means, the substances of natural or synthetic origin present in a heritage object or industrial material. This characterization technique mainly targets :

  • Absorbed or deposited organic residues (fats, oils, waxes, proteins);
  • Binders and varnishes used in paint coats or finishes;
  • Biobased compounds used in the formulation of industrial polymers.

In the art market, it can be used to assess the historical and technological coherence of an object, or to authenticate a work of art. In archaeology, it provides functional information on past uses (containers, rituals, techniques). In an industrial context, it provides guarantees on the composition, origin or conformity of a material.

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Unrolling a papyrus scroll to verify the authenticity of the artwork

Means used to characterize organic materials

CIRAM uses several complementary methods, selected according to the nature of the samples and the objectives of the study:

  • Raman spectroscopy, particularly suited to the identification of polymers, resins, waxes or varnishes, directly on the object or from a micro-sample.
  • FTIR (Fourier Transform Infrared) spectroscopy enables rapid identification of functional groups present in organic compounds. Effective for complex mixtures and degraded materials.
  • Gas chromatography coupled with mass spectrometry (GC-MS) provides in-depth analysis of organic mixtures (natural resins, oils, binders, waxes), enabling comparison with reference databases.
  • Elemental analysis coupled with isotope ratio mass spectrometry (EA-IRMS) provides isotopic signatures for carbon (¹³C/¹²C) and nitrogen (¹⁵N/¹⁴N). This method is used to determine the biological origin of a material or to assess the biobased content according to ISO 16620-2.

These methods can be used alone or in combination to obtain robust results that can be exploited in a heritage or industrial context.

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Residues, binders, varnishes :
materials with a high index value

01 - Organic residues on archaeological objects

In the archaeologyorganic residues absorbed or encrusted on ceramics, tools or ritual objects provide valuable information on past uses:

  • Nature of products contained (oils, resins, fats, etc.),
  • Processing and preservation methods,
  • Exploited plant or animal sources.

Using GC-MS or FTIR analysis, CIRAM helps archaeologists to reconstruct the food, medicinal and craft practices of ancient civilizations.

02 - Binders and varnishes in works of art

In the art marketthe identification of binders or varnishes (natural resins, drying oils, waxes, animal glues) makes it possible to authenticate works of art and date their creation. Certain chemical signatures are characteristic of specific periods, geographical areas or workshops.

Raman or FTIR spectra can be used to identify these components, and their comparison with historical reference databases refines the analysis.

03 - Industrial waxes and bio-based materials

For industryparticularly in the packagingtextile and polymer sectors, elemental and isotopic analysis (EA-IRMS) can be used to :

  • Check the natural or synthetic origin of materials,
  • Determine the biobased content (in accordance with ISO 16620-2),
  • Check product compliance with regulatory or environmental requirements.

CIRAM, expert in organic materials analysis

When you call on CIRAM for your organic analyses, you benefit from recognized expertise, scientific rigor and cutting-edge analytical technologies.
CIRAM relies on :

  • Highly sensitive and complementary instruments (Raman, FTIR, GC-MS, EA-IRMS),
  • Reference databases for reliable interpretation of spectra,
  • A multidisciplinary team capable of combining different techniques - spectrometry, microanalysis, metallographychromatography, X-ray radiography - to offer a rigorous, contextualized interpretation of results.
  • Validated protocols to guarantee reproducibility and traceability of results.

CIRAM supports museum institutions, archaeologists, auction houses, art restorers and manufacturers in their projects in France and abroad.

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Are you asking yourself these questions?

Is it possible to analyze a varnish on an old painting?

Yes, FTIR or GC-MS analysis can identify the exact nature of the varnish, whether natural (dammar, mastic...) or synthetic.

Can a wax be authenticated?

Yes, chromatographic analysis identifies its composition (bee, carnauba, synthetic...) and can reveal its origin or use.

Does this technique damage the object being analyzed?

Non. Les méthodes sont non-destructives ou requièrent seulement un micro-prélèvement (<1 mg) selon les cas.

Is it possible to authenticate a work of art using organic analysis?

Yes, binders and varnishes are reliable indicators of any anachronisms or chemical signatures specific to a particular period.

How much does an analysis of organic materials cost?

The cost depends on the number of techniques used, the type of object, the nature of the sample and the degree of interpretation required. Contact us for a personalized quote.

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